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Unfortunaely Gledhill dont seem to have an answer, the engineer I am using came on recomendation from Gledhill and has apparetly installed hundreds of similar systems....OK, that's a bit of important information .... you are using a pumped accumulator running @ ~ 2bar. Is it an ST?
As a first, the engineer should be looking to align the pre-charge closer to the input pressure to minimise the differential once the cylinder is fully heated. It sounds like there is a 'sweet spot' with the EV where the pressure release through the EV's baffle is causing a resonance, creating the 'fog horn' noises. You did say that a new PRV/Control group was installed? That would generally rule out the PRV. It may also be an idea to calibrated the PRV closer to the Accumulator's output.
I'm afraid to say though, you could really do with an engineer that is experienced with working with these types of systems, especially when yours is a bit of a hybrid, using an accumulator. This is really UV/EV 1'o'1 and he should be running through all of this stuff. That being said, Gledhill should also be asking the right questions and you shouldn't really have to rely on a forum to get to the bottom of it all for you, not that giving you advice is any issue it's just a long drawn out process for you and it shouldn't need to be.
You really need someone that can work through all of this at one visit, rather than having to come back here once something is tried but doesn't work.
The cold water water has a precharge of 4bar but the incoming main has an adjustable monoblock pressure reducing value with up and downstream gauges on.
It's a Stuart Turner Mainsboost system and we have tinkered about with the pressure (from 2.0-3.0bar) but that hasnt really made much difference.
Engineer is coming back in a couple of weeks and is talking about putting a secondary expansion vessell in (not sure where though)
Bit that is most confusing for me is if we drain the system de-pressurise the EV then re-set it all the noise goes away for a few weeks then slowly returns and continues to get worse!
Really appreciate all the comments and help though so at lease I can challenge/make suggestions to the engineer