8 is taking 240 from LI don't know why 8 is boiler, when it should be Com. Have a look at this attachment
When HW is on 6 runs the boiler and feeds live to 5 also. If CH slider on position then pump will run if HW time is calling
If HW is not calling, no CH either.
There is a better way to do this where ch operation starts the boiler and pump or hw only operates the boiler to heat hot water.
As said above, installing a 28mm MV improves the system
