If you increased the boiler pressure to 1.5bar while cold and it then fell to 1.0bar then you will have lost a substantial 2.4L. IF "So the pressure swings from 1 bar (boiler turned off) to 1.5/1.6 bar (boiler fired on)." and if that means that the cold pressure is 1.0bar and the hot pressure is 1.6bar with the system up to temperature and then returns to 1.0bar when cold then that suggests that the charging/filling pressures are the same (at 1.0bar) so this would be normal under these conditions.. You should ensure no pressure at the EV water (boiler) end, then get a tyre pressure gauge and check the EV air end pressure at the schrader valve, ensure its (air) pressurized to 1.0bar, fill/pressurize the water end to 1.5bar and monitor it again, the pressure should rise to ~ 2.6bar when hot and reduce to 1.5bar when fully cold, if it eventually reduces again to 1.0bar then you have a leak somewhere as there is nothing coming from the pressure relief valve. The leak might be from the boiler combustion chamber, you might then see a leak into the condensate trap.