OK. If I assume that the factors Cg (grouping), Cs (soil thermal resistivity) and Cd (depth) are all 1, that the soil ambient temp is 20° (hence Ca=1), and that the CCC of buried (method D) 50mm² SWA at 70° is 140A, then for 60A I get the 'VD correction factor' (C1) as 0.9755. If that's right, it means that (based on the 70° VD of 7.53V), the VD at 60A should be 7.34V - still way above your software's 6.65V. So, either I've done my sums wrong or else we need to find some other explanation.
Sorry, folks (particularly Lectrician) - I got my arithmetic wrong somewhere

Using above assumptions, the 'VD correction factor' (C1) should have been 0.891, which turns the VD (per BS7671 70° figures) of 7.53V into about 6.7V, therefore very close to the answer produced by Lectrician's software - which therefore
is pretty clever. Apologies for the slight hiccup with the maths!
Kind Regards, John