Probably not what you want to hear but I would stop what you are doing before you damage the existing controller, the boiler or both.
Those pro E plugs are not designed to hold two cores of the size you are using either.
Once you are clear about what is or is not installed and if you choose to use your new stat you need to decide on mains or 24V control and cable appropriately.
I suggest you use mains as cabling is simpler stat terms are 1 -L, 2-N, 3 not used, 4 - L (linked from 1), 5 - to RT boiler input on turquoise plug.
The X41 connector shown in your manual excerpt is for an outside temperature sensor and is not relevant to your new stat, only Ebus weather comp controls
Those pro E plugs are not designed to hold two cores of the size you are using either.
Once you are clear about what is or is not installed and if you choose to use your new stat you need to decide on mains or 24V control and cable appropriately.
I suggest you use mains as cabling is simpler stat terms are 1 -L, 2-N, 3 not used, 4 - L (linked from 1), 5 - to RT boiler input on turquoise plug.
The X41 connector shown in your manual excerpt is for an outside temperature sensor and is not relevant to your new stat, only Ebus weather comp controls

