It only needs to survive hot water, not flames. I suspect that any normal filler would work. As above, fill most of the hole with a suitably whittled bit of wood, glued or screwed in maybe, then filler, then sand flat and paint.
Expansion and contraction, might be an issue. An easy way to allow for that, is to slit a piece of close-fitting plastic pipe, to act as a sleeve, for the pipe.

