Most people with that set up just leave the DHW on 24/7. A modern cylinder with a big enough coil to run PDHW usually has a heat loss low enough that it doesn't matter
I prefer it not to come on during the night hours, to give the cylinder a quick boost. I have it set to come on at 1500, off at 2000, which normally means we have water hot for baths in the early evening, washing up, and any used hot, is topped up, for next day, plus plenty of hot still available next morning. Coming on at 1500, means the house will be warm, so the ch going off for 30 minutes, will not be noticed.
