In no particular order ...
The original question. What the OP wants is impossible, because his question is wrong. He asks for an S plan, but wants extras - that means it's no longer an S plan by definition, since an S plan is a specific combination of motorised valves
and wiring.
However, without having paid too much attention to it, I'm assuming the boiler has some terminals to which one can attach a sensor and it will vary it's output temperature. In that case, one or other of the valves has it's switch connected to trigger a relay instead of the boiler/pump. The relay has two sets of contacts - one fires the boiler/pump as would be done directly by the switch in the original S plan, the other applies a suitable resistance to change the boiler temperature.
I think someone else has also come up with the issue of interlocking the CH and DHW - otherwise you have to choose between having high CH or poor DHW reheat when both are demanded.
EDIT: that can be dealt with by judicious wiring of the controller switches and/or relay to lock out one circuit while the other is running. That then means you have to decide which has the higher priority.
As to Mysons, they used them at my last place and I pointed out that from the control POV they are horribly inefficient. Eventually when we put in some cooling, I rigged up the controls so that heating was controlled by a thermo-hydraulic valve in the supply, and the fan switched on/off with the internal pipe stat. So the heating/cooling controller would switch on the heater in the valve head, the valve would open, and the hot water would trigger the pipe stat in the Myson to turn on the fan. Once the desired temp was reached, the valve would be turned off, and when the flow stopped, the Myson would cool off and turn itself off.
But I'd answer the original question differently. I'd design a hydraulic system that wasn't fundamentally crap to start with. As has been pointed out - we seem to have a fixation with making one thing do two jobs with widely differing (and often conflicting) requirements. A prime example is the Combi Boiler which requires huge capacities for DHW, but then is grossly oversized for CH - take my flat for example, 30kW combi is **** poor at heating DHW, but is also **** poor at ranging down enough to supply CH at 2kW in the depths of winter (and a lot less in milder weather).
We also impose minimum flow rates through the boiler, when we know that we need variable (and often low) flow rates through the CH system.
Anyway, the solution I chose was to install a thermal store. Boiler is directly connected and heat the store by burning at full power and then shutting down completely in between. When the boiler gets replaced, that will also mean no pilot light.
The CH is supplied by a modulating pump and individual room temps are controlled by TRVs - there is no permanently open rad, and no bypass, so the flow rate through the CH system is what is needed as determined by the TRVs, no more and no less.
The supply to the CH pump is via a TMV which blends cool return with hot from the store to control flow temperature. Not ideal, and I do have some ideas in terms of better control with electronics.
With oversized rads, the return temp (ie what's going back in the bottom of the store) is barely above room temp.
DHW is via a heat exchanger coil that winds it's way up from the bottom of the store to the top - with the DHW gaining heat all the way. This means the cold mains will be heated by even the low grade heat in the bottom of the store (ie return from the rads). In practice, this also means the store temperature varies with position - by the time the hot water reaches the CH tap off, it's already been used for heating the DHW and is cooler than it was when it came in from the boiler.
Unfortunately, the next bit is where the boiler manufacturers are a bunch of cretins. My ideal would be to control flow rate so the boiler can heat from cold (could be 20˚ or even lower) to hot (perhaps 75˚, depends on various factors) in one pass. With the condenser handling water at (say) 20˚, it'll both condense very well, and also extract more specific heat from the exhaust. However, all the manufacturers have a maximum delta-T of 20˚ AFAICS - so that means using diverter or mixer valves to artificially increase the return temperature and reduce efficiency.
I've heard that Atmos claim their boilers can be dry-fired without damage due to a large heat exchanger and sensing directly in it - but their MIs still have this max 20˚ delta-T. When it comes to new boiler time, I'll be asking the manufacturers and see if any of them are capable of supplying usable products.
As a side effect, but one that did influence my decision, the thermal store also has an immersion heater. So not only can the DHW be supplied by electric in the event of a boiler problem, but so can the heating
Dunno if solar thermal will ever happen as it's not a good location, but if I did fit it, then with the vey low store temperatures in the bottom where the solar coil is, that should allow good performance even with low insolation levels.