The evaporator is underneath the steam turbine, it causes a part vacuum, the problem is cooling the water, hence huge cooling towers, the hotter the water going into the boiler the less energy is required to turn it into steam. In theory I will admit one could extract energy from the flue gases, but what is more important is to remove particular emissions, so yes the flue gases are often cooled but in the main to remove nasty stuff rather than gain the latent heat, and it is not done in the boiler, the scrubbers are well after the boiler.
Low temperature water heaters may use the energy form the latent heat, but super heated steam boilers would not have this built into the boiler, if it exists it would be a separate unit.
I know the one I was involved in, the waste heat was used to make the steam, as the gas burns the expansion drives the gas turbine, then it makes super heated steam which is fed to the steam turbine, and then into the scrubber to remove nasties.
The domestic water heater 1) does not boil the water. 2) it does not use the expansion of the gas as it burns, and 3) it does not catch the nasties and store them for safe disposal. I am sure there were domestic central heating boilers, but I have never seen one, except when there was a fault.