I set my devices to turn on late rather than early, if I look at my own use
View attachment 405275 at midnight battery discharged, so there is some grid usage, but I don't start the charge of the batteries until 1:30 am, as I know they will be fully charged by 3:30 am, so since I have off-peak until 5:30 am I have 2 hours leeway.
Now with storage radiators they likely take longer, but like with my batteries this shows
View attachment 405276 that only 5 hours are required, and they have 7, so no harm in starting the charging of the storage heat battery late, it seems however looking at around 1.35 kWh per day, so peak - off-peak in my case is 31.94-8.50 = 23.44p/kWh extra x 1.35 = 31.644p and a timer able to handle 3 kW costs around £10, so 32 days to pay for its self.
However, need to work out totals first, not sure a single storage heater pays for its self to start with? For every month I get one of these

so average 13.616p/kWh so that for me is far lower than the 26.91p/kWh standard rate. For me, the difference is so massive, no real need to do all months, I can easily see the split tariff is better for me.
But with storage heaters, in summer Economy 7 will not save anything. In fact, it will likely cost more, so before spending out on timers, need to be sure it is going to pay. With my heating, I select when I want to heat, and to only heat as and when required.