Generally plastic fuel tanks are used (I guess) because they melt and will not BLEVE....
You believe wrong. They are used because they can be manufactured more easily to complex shapes with less process steps. Making a metal tank requires multiple steps - pressing out the parts and assembling them. Making a plastic tank of arbitrary shape merely means making the roto mould for it and then production is just two steps - mould, trim.
Either will burst if the vents are faulty, ie both can create a BLEVE.
Incidentally, what you consider to be the explosion is not in fact an explosion. The explosion is the rapid pressure rise and release which can create a shockwave. The fireball that follows if the contents are flammable is just that - a fireball and not an explosion (the fuel/air mixture will be far to rich for rapid flame propagation). I have in fact witnessed one BLEVE, quite impressive though being water/steam there wasn't a followup fireball.
A reasonable definition of an explosion is a rapid increase in volume and energy which is what I believe we saw...
Wrong again, what you saw was rapid combustion, not detonation. Look up the definition : A violent expansion in which energy is transmitted outward as a shock wave.
I'm sorry that you were disappointed that no windows were broken but if the vehicle was in motion I'm sure that the driver would have been suitably startled. I have no doubt that you would have calmly pulled over in a safe place and extinguished your hair before continuing your journey, miffed that your air conditioning didn't work.
Au contrair, my first reaction wouldn't be to light a match
Didn't you notice that the gas did
not ignite before he lit the match ? In fact they were moving around taking readings and it didn't go up until he lit the match.
So, if mine went up (and I don't have a car with A/C at the moment anyway) I'd simply wind down the window (or crack the door*) and by the time I'd come to a controlled stop the gas would have dispersed below combustible levels. It wouldn't ignite, there's nothing inside the vehicle hot enough to do so - and yes, I do know how hot you need your sparks, poor ignition is a significant issue with LPG conversions.
Of much higher risk than the inferno - that didn't happen until the guy lit a match - is the "surprise factor" when the cabin fills with cloud which would happen with any refrigerant.
I do find it a little worrying that you are happy to bodge your car rather than to carry out a good quality retrofit to your car, I'm sure that your attitude doesn't extend to your professional life
Actually you admit yourself that propane is a recognised refrigerant. It has low environmental effects, is non toxic**, is readily available, and handled properly is quite safe. I realise you are scared of it - I'm not because I understand the concept of risk, and I understand that nothing in life is risk free and never will be in spite of what some numpties want.
But this is all completely irrelevant to the OP's question, I said ages ago that I'm happy to agree to disagree, but you seem to want to drag on with your emotional drivel (sorry, that's what it's turning into)
* Yes, it may surprise you to know that you can safely open a door while in motion - it's a lot quicker than opening a window.
** Though it does have other effects.