Yes indeed. I would have got back earlier but today was a mad, mad, mad, mad day!
Cables one and two are permanent live and neutral. One brings power in and the other takes it on to the next light. Keep their browns tied together or other lights will stop working. Note that we don't know which one is the supply at this point and it doesn't really matter.
Cable 3 is switched live to one of your lights. Leave this one where it is.
Cable 4 is switched live to the other light. Move its brown wire to L1 bottom.
Cable 5, as you suspect, goes to the single switch. Remove all three cores and put them in choc block for now but be sure you know where they came from just in case you have to put everything back and start again.
You should now have two lights controlled by the two switches in that double. All other lights should work as before. If this is the case you can be 99.9% sure that the three core cable is isolated but I prefer 100%. Connect its three cores together then connect a light bulb between them and the neutral block. Switch the two lights on. If the extra bulb lights up my final 0.1% is vindicated - but it won't.
At the single switch end, put brown and black into Live In and Neutral In on a new, fused, two pole switch. Sleeve the black with blue and isolate grey. Back at the double switch, put the brown core into L2 top. Sleeve the black one blue and put it into the neutral block. Isolate the grey one. You can now connect your outside light to the other side of the fused switch.